KIT - SAFETY DATA SHEET   
Product identifier used on the label:
Kit Name DEVCON® Plastic Welder™ straw [1:1]
Stock No.: 14300
 
Other means of identification:
 
Recommended use of the chemical and restrictions on use:
 
Chemical manufacturer address and telephone number:
Manufacturer Name: ITW Polymers Adhesives, North America
Address: 30 Endicott Street
Danvers, MA 01923
General Phone Number: (978) 777-1100
 
Emergency phone number:
Emergency Phone Number: (800) 424-9300
CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424-9300

Component list
Component B  MA300 / MA310 ACTIVATOR
Component A  MA300 ADHESIVE
Kit SDS Revision Date 08/24/2015
Print
MSDS
Component B - SDS   
SECTION 1 : IDENTIFICATION
Product identifier used on the label:
Product Name: MA300 / MA310 ACTIVATOR
 
Other means of identification:
Synonyms: None.
 
Recommended use of the chemical and restrictions on use:
Product Use/Restriction: Not applicable.
 
Chemical manufacturer address and telephone number:
Manufacturer Name: ITW
Address: 30 Endicott Street
Danvers, MA 01923
General Phone Number: (978) 777-1100
 
Emergency phone number:
Emergency Phone Number: (800) 424-9300
CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424-9300
SECTION 2 : HAZARD(S) IDENTIFICATION
Classification of the chemical in accordance with CFR 1910.1200(d)(f):
GHS Pictograms:
Signal Word: DANGER.
GHS Class: Flammable Liquid. Category 2.
Skin Irritation. Category 2.
Skin Sensitization. Category 1.
Specific Target Organ Toxicity - STOT, Single Exposure SE. Category 3.
Hazard Statements: H225 - Highly flammable liquid and vapor.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H335 - May cause respiratory irritation.
Precautionary Statements: P210 - Keep away from heat/sparks/open flames/hotsurfaces. — No smoking.
P233 - Keep container tightly closed.
P240 - Ground/Bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash hands thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P321 - Specific treatment (see ... on this label).
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use dry chemical, carbon dioxide to extinguish small fires. Use water for large fires.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/container in accordance with Local, State, Federal and Provincial regulations.
Hazards not otherwise classified that have been identified during the classification process:
Route of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
    Eye: Can cause moderate irritation, burning sensation, tearing, redness, and swelling. Overexposure may cause lacrimation, conjunctivitis, corneal damage and permanent injury.
    Skin: Can cause skin irritation; itching, redness, rashes, hives, burning, and swelling. Allergic reactions are possible.
May cause skin sensitization, an allergic reaction, which becomes evident on reexposure to this material.
    Inhalation: Respiratory tract irritant. High concentration may cause dizziness, headache, and anesthetic effects.
    Ingestion: Causes irritation, a burning sensation of the mouth, throat and gastrointestinal tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe reddening, swelling, and possible tissue destruction.
Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting.
Target Organs: Eyes. Skin. Respiratory system. Digestive system. Liver. Kidney. Olfactory Function.
Aggravation of Pre-Existing Conditions: Individuals with pre-existing skin disorders, asthma, allergies or known sensitization may be more susceptible to the effects of this product.
SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures:
Chemical Name CAS# Ingredient Percent     EC Num. 
Methyl Methacrylate Monomer 80-62-6    70 - 80 by weight    
Poly (acrylonitrile-butadiene-styrene) 9003-56-9    1 - 10 by weight    
Acrylic-butadiene-styrene terpolymer 25852-37-3    1 - 10 by weight    
Proprietary ingredient(s) Trade Secret    1 - 10 by weight    
3,5-Diethyl-1,2-dihydro-1-phenyl-2-propylpyridine 34562-31-7    1 - 10 by weight    

SECTION 4 : FIRST AID MEASURES
Description of necessary measures:
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while removing contaminated clothing and shoes. Get medical attention if irritation develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person.
SECTION 5 : FIRE FIGHTING MEASURES
 
Suitable and unsuitable extinguishing media:
Suitable Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this material.
Unsuitable extinguishing media: Water may cause frothing.
Unusual Fire Hazards: Sealed containers at elevated temperatures may rupture explosively and spread fire due to polymerization.
 
Special protective equipment and precautions for fire-fighters:
Protective Equipment: As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH (approved or equivalent) and full protective gear.
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire exposed containers to minimize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water.
Vapors can flow along surfaces to distant ignition sources and flash back.
SECTION 6 : ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures:
Personal Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area.
Environmental precautions:
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Methods and materials for containment and cleaning up:
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a chemical waste container. Provide ventilation. Collect spill with a non-sparking tool. Place into a suitable container for disposal. Clean up spills immediately observing precautions in the protective equipment section. After removal, flush spill area with soap and water to remove trace residue.
Flammable, eliminate ignition sources. Vapors can form an ignitable mixture with air. Vapors can flow along surfaces to distant ignition sources and flash back. Ventilate area. Use proper personal protective equipment as listed in Section 8.
Reference to other sections:
Other Precautions: Pump or shovel to storage/salvage vessels. Add inhibitor to prevent polymerization.
SECTION 7 : HANDLING and STORAGE
Precautions for safe handling:
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Material will accumulate static charges which may cause an electrical spark (ignition source). Use proper grounding procedures. Do not reuse containers without proper cleaning or reconditioning.
Hygiene Practices: Wash thoroughly after handling.
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition products (see Section 10) during welding/flame cutting operations and to protect against dust during sanding/grinding of cured product. Hazardous liquid or vapor residue may remain in emptied container. Do not reuse, heat, burn, pressurize, cut, weld, braze, solder, drill, grind, expose to sparks, flame, or ignition sources of empty containers without proper commercial cleaning or reconditioning.
Conditions for safe storage, including any incompatibilities:
Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible materials, direct sunlight, and incompatible substances. Keep container tightly closed when not in use.
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
EXPOSURE GUIDELINES:
Methyl Methacrylate Monomer :
Guideline ACGIH: TLV-STEL: 100 ppm
TLV-TWA: 50 ppm
Sensitizer.
Guideline OSHA: PEL-TWA: 100 ppm
Appropriate engineering controls:
Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment.
Individual protection measures:
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face protection regulation, or the European standard EN 166.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent skin contact. Consult manufacturer's data for permeability data.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash and a deluge shower safety station.
Notes : Only established PEL and TLV values for the ingredients are listed.
SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES
PHYSICAL AND CHEMICAL PROPERTIES:
Physical State Appearance: Paste.
Odor: Fragrant.
Boiling Point: 213°F (100.5°C)
Melting Point: Not determined.
Specific Gravity: 0.96
Solubility: Not determined.
Vapor Density: 3.5 (air = 1)
Vapor Pressure: 28 mmHg @68°F
Percent Volatile: Not determined.
Evaporation Rate: 3 (butyl acetate = 1)
pH: 4.5-5.5 @ 5 Percent Solution
Molecular Formula: Mixture
Molecular Weight: Mixture
Flash Point: 50°F (10°C)
Flash Point Method: Tag closed cup. (TCC)
Lower Flammable/Explosive Limit: 2.1%
Upper Flammable/Explosive Limit: 12.5%
Auto Ignition Temperature: Not determined.
VOC Content: <50 g/L mixed.
9.2. Other information:
Percent Solids by Weight Not determined.
SECTION 10 : STABILITY and REACTIVITY
Chemical Stability:
Chemical Stability: Unstable.
Possibility of hazardous reactions:
Hazardous Polymerization: Polymerization may occur under certain conditions.
Conditions To Avoid:
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and oxidizing conditions. Oxygen-free atmospheres or inert gas blanketing. Freezing conditions. Material can soften paint and rubber.
Incompatible Materials:
Incompatible Materials: Oxidizing agents (eg peroxides, nitrates), reducing agents, acids, bases, azo-compounds, catalytic metals (eg copper, iron), halogens. Free radical initiators. Oxygen scavengers.
SECTION 11 : TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION:

Methyl Methacrylate Monomer :
Eye: Administration into the eye - Rabbit Standard Draize test: 150 mg [Not reported.] (RTECS)
Skin: Administration onto the skin - Rabbit LD50 - Lethal dose, 50 percent kill: >5 gm/kg [Skin and Appendages - Dermatitis, other(After systemic exposure) ] (RTECS)
Inhalation: Inhalation - Rat LC50 - Lethal concentration, 50 percent kill: 78000 mg/m3/4H [Details of toxic effects not reported other than lethal dose value] (RTECS)
Ingestion: Oral - Rat LD50 - Lethal dose, 50 percent kill: 7872 mg/kg [Behavioral - Muscle weakness Behavioral - Coma Lungs, Thorax, or Respiration - Respiratory depression] (RTECS)
SECTION 12 : ECOLOGICAL INFORMATION
Ecotoxicity:
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
SECTION 13 : DISPOSAL CONSIDERATIONS
Description of waste:
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines.
RCRA Number: D001
Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may spontaneously catch fire if improperly discarded or stored. To avoid a spontaneous combustion fire, immediately after use, place rags, steel wool or waste in a sealed, water-filled, metal container.
SECTION 14 : TRANSPORT INFORMATION
DOT Shipping Name: Refer to Bill of Lading
DOT UN Number: Refer to Bill of Lading
IATA Shipping Name: Refer to Bill of Lading
IATA UN Number: Refer to Bill of Lading
IMDG UN Number : Refer to Bill of Lading
IMDG Shipping Name : Refer to Bill of Lading
SECTION 15 : REGULATORY INFORMATION
Safety, health and environmental regulations specific for the product:
Methyl Methacrylate Monomer :
TSCA Inventory Status: Listed
Section 313: EPCRA - 40 CFR Part 372 - (SARA Title III) Section 313 Listed Chemical.
Canada DSL: Listed
Poly (acrylonitrile-butadiene-styrene) :
TSCA Inventory Status: Listed
Canada DSL: Listed
Acrylic-butadiene-styrene terpolymer :
TSCA Inventory Status: Listed
Canada DSL: Listed
3,5-Diethyl-1,2-dihydro-1-phenyl-2-propylpyridine :
TSCA Inventory Status: Listed
Canada DSL: Listed
Canadian Regulations. WHMIS Hazard Class(es): B2; D2B
All components of this product are on the Canadian Domestic Substances List.
WHMIS Pictograms:
SECTION 16 : ADDITIONAL INFORMATION
HMIS Ratings:
HMIS Health Hazard: 2*
HMIS Fire Hazard: 3
HMIS Reactivity: 2
HMIS Personal Protection: X
Health Hazard    2*
Fire Hazard    3
Reactivity    2
Personal Protection    X
*  Chronic Health Effects
SDS Revision Date: May 19, 2015
MSDS Revision Notes: GHS Update
MSDS Author: Actio Corporation
Disclaimer: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. ITW Polymers Adhesives, NA, MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the ITW Polymers Adhesives, NA product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a ITW Polymers Adhesives, NA product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the ITW Polymers Adhesives, NA product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. ITW Polymers Adhesives, NA provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, ITW Polymers Adhesives, NA makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from ITW Polymers Adhesives, NA
 
Copyright© 1996-2015 Actio Corporation. All Rights Reserved.


MSDS
Component A - SDS   
SECTION 1 : IDENTIFICATION
Product identifier used on the label:
Product Name: MA300 ADHESIVE
 
Other means of identification:
Synonyms: None.
 
Recommended use of the chemical and restrictions on use:
Product Use/Restriction: Not applicable.
 
Chemical manufacturer address and telephone number:
Manufacturer Name: ITW
Address: 30 Endicott Street
Danvers, MA 01923
General Phone Number: (978) 777-1100
 
Emergency phone number:
Emergency Phone Number: (800) 424-9300
CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424-9300
SECTION 2 : HAZARD(S) IDENTIFICATION
Classification of the chemical in accordance with CFR 1910.1200(d)(f):
GHS Pictograms:
Signal Word: DANGER.
GHS Class: Flammable Liquid. Category 2.
Serious Eye Damage. Category 1.
Skin corrosion. Category 1.
Germ cell mutagenicity. Category 2.
Skin Sensitization. Category 1.
Specific Target Organ Toxicity - STOT, Single Exposure SE. Category 3.
Hazard Statements: H225 - Highly flammable liquid and vapor.
H318 - Causes serious eye damage.
H314 - Causes severe skin burns and eye damage.
H341 - Suspected of causing genetic defects.
H317 - May cause an allergic skin reaction.
H335 - May cause respiratory irritation.
Precautionary Statements: P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat/sparks/open flames/hotsurfaces. — No smoking.
P233 - Keep container tightly closed.
P240 - Ground/Bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P260 - Do not breathe dust/fume/gas/mist/vapours/spray.
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash hands thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do not induce vomiting.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P310 - Immediately call a POISON CENTER or doctor/physician.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P321 - Specific treatment (see ... on this label).
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P363 - Wash contaminated clothing before reuse.
P370+P378 - In case of fire: Use dry chemical, carbon dioxide to extinguish small fires. Use water for large fires.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/container in accordance with Local, State, Federal and Provincial regulations.
Hazards not otherwise classified that have been identified during the classification process:
Route of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
    Eye: Can cause moderate irritation, burning sensation, tearing, redness, and swelling. Overexposure may cause lacrimation, conjunctivitis, corneal damage and permanent injury.
    Skin: Can cause skin irritation; itching, redness, rashes, hives, burning, and swelling. Allergic reactions are possible.
May cause skin sensitization, an allergic reaction, which becomes evident on reexposure to this material.
    Inhalation: Respiratory tract irritant. High concentration may cause dizziness, headache, and anesthetic effects.
    Ingestion: Causes irritation, a burning sensation of the mouth, throat and gastrointestinal tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe reddening, swelling, and possible tissue destruction.
Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting.
Target Organs: Eyes. Skin. Respiratory system. Digestive system. Liver. Kidney. Olfactory Function.
Aggravation of Pre-Existing Conditions: Individuals with pre-existing skin disorders, asthma, allergies or known sensitization may be more susceptible to the effects of this product.
SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures:
Chemical Name CAS# Ingredient Percent     EC Num. 
Methacrylic acid 79-41-4    1 - 10 by weight    
Methyl Methacrylate Monomer 80-62-6    50 - 60 by weight    
Chlorosulfonated polyethylene 68037-39-8    20 - 30 by weight    
Proprietary ingredient(s) Trade Secret    10 - 20 by weight    
Magnesium silicate hydrate 14807-96-6    0.1 - 1.0 by weight    
Diglycidyl Ether of Bisphenol A 1675-54-3    0.1 - 1.0 by weight    
Hydroquinone 123-31-9    0.1 - 1.0 by weight    

SECTION 4 : FIRST AID MEASURES
Description of necessary measures:
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while removing contaminated clothing and shoes. Get medical attention if irritation develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person.
SECTION 5 : FIRE FIGHTING MEASURES
 
Suitable and unsuitable extinguishing media:
Suitable Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this material.
Unsuitable extinguishing media: Water may cause frothing.
Unusual Fire Hazards: Sealed containers at elevated temperatures may rupture explosively and spread fire due to polymerization.
 
Special protective equipment and precautions for fire-fighters:
Protective Equipment: As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH (approved or equivalent) and full protective gear.
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire exposed containers to minimize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water.
Vapors can flow along surfaces to distant ignition sources and flash back.
SECTION 6 : ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures:
Personal Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area.
Environmental precautions:
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Methods and materials for containment and cleaning up:
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a chemical waste container. Provide ventilation. Collect spill with a non-sparking tool. Place into a suitable container for disposal. Clean up spills immediately observing precautions in the protective equipment section. After removal, flush spill area with soap and water to remove trace residue.
Flammable, eliminate ignition sources. Vapors can form an ignitable mixture with air. Vapors can flow along surfaces to distant ignition sources and flash back. Ventilate area. Use proper personal protective equipment as listed in Section 8.
Reference to other sections:
Other Precautions: Pump or shovel to storage/salvage vessels. Add inhibitor to prevent polymerization.
SECTION 7 : HANDLING and STORAGE
Precautions for safe handling:
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Material will accumulate static charges which may cause an electrical spark (ignition source). Use proper grounding procedures. Do not reuse containers without proper cleaning or reconditioning.
Hygiene Practices: Wash thoroughly after handling.
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition products (see Section 10) during welding/flame cutting operations and to protect against dust during sanding/grinding of cured product. Hazardous liquid or vapor residue may remain in emptied container. Do not reuse, heat, burn, pressurize, cut, weld, braze, solder, drill, grind, expose to sparks, flame, or ignition sources of empty containers without proper commercial cleaning or reconditioning.
Conditions for safe storage, including any incompatibilities:
Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible materials, direct sunlight, and incompatible substances. Keep container tightly closed when not in use.
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
EXPOSURE GUIDELINES:
Methacrylic acid :
Guideline ACGIH: TLV-TWA: 20 ppm
Methyl Methacrylate Monomer :
Guideline ACGIH: TLV-STEL: 100 ppm
TLV-TWA: 50 ppm
Sensitizer.
Guideline OSHA: PEL-TWA: 100 ppm
Magnesium silicate hydrate :
Guideline ACGIH: TLV-TWA: 1 mg/m3 Respirable fraction (R)
Guideline OSHA: PEL-TWA: 20 mppcf
Hydroquinone :
Guideline ACGIH: TLV-TWA: 1 mg/m3
TLV-TWA: 1 mg/m3
Sensitizer.: Sen
Sensitizer.
Guideline OSHA: PEL-TWA: 2 mg/m3
Appropriate engineering controls:
Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment.
Individual protection measures:
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face protection regulation, or the European standard EN 166.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent skin contact. Consult manufacturer's data for permeability data.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash and a deluge shower safety station.
Notes : Only established PEL and TLV values for the ingredients are listed.
SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES
PHYSICAL AND CHEMICAL PROPERTIES:
Physical State Appearance: Paste.
Color: off-white.
Odor: Fragrant.
Boiling Point: 213°F (100.5°C)
Melting Point: Not determined.
Specific Gravity: 1.0
Solubility: Not determined.
Vapor Density: > 1 (air = 1)
Vapor Pressure: 28 mmHg @68°F
Percent Volatile: Not determined.
Evaporation Rate: 3 (butyl acetate = 1)
pH: 3.0-3.5 @ 5 Percent Solution
Molecular Formula: Mixture
Molecular Weight: Mixture
Flash Point: 50°F (10°C)
Flash Point Method: Tag closed cup. (TCC)
Lower Flammable/Explosive Limit: 2.1%
Upper Flammable/Explosive Limit: 12.5%
Auto Ignition Temperature: Not determined.
VOC Content: <50 g/L mixed.
9.2. Other information:
Percent Solids by Weight Not determined.
SECTION 10 : STABILITY and REACTIVITY
Chemical Stability:
Chemical Stability: Unstable.
Possibility of hazardous reactions:
Hazardous Polymerization: Polymerization may occur under certain conditions.
Conditions To Avoid:
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and oxidizing conditions. Oxygen-free atmospheres or inert gas blanketing. Freezing conditions. Material can soften paint and rubber.
Incompatible Materials:
Incompatible Materials: Oxidizing agents (eg peroxides, nitrates), reducing agents, acids, bases, azo-compounds, catalytic metals (eg copper, iron), halogens. Free radical initiators. Oxygen scavengers.
SECTION 11 : TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION:

Methacrylic acid :
Skin: Administration onto the skin - Rabbit LD50 - Lethal dose, 50 percent kill: 500 mg/kg [Details of toxic effects not reported other than lethal dose value] (RTECS)
Ingestion: Oral - Rat LD50 - Lethal dose, 50 percent kill: 1060 mg/kg [Details of toxic effects not reported other than lethal dose value] (RTECS)
Methyl Methacrylate Monomer :
Eye: Administration into the eye - Rabbit Standard Draize test: 150 mg [Not reported.] (RTECS)
Skin: Administration onto the skin - Rabbit LD50 - Lethal dose, 50 percent kill: >5 gm/kg [Skin and Appendages - Dermatitis, other(After systemic exposure) ] (RTECS)
Inhalation: Inhalation - Rat LC50 - Lethal concentration, 50 percent kill: 78000 mg/m3/4H [Details of toxic effects not reported other than lethal dose value] (RTECS)
Ingestion: Oral - Rat LD50 - Lethal dose, 50 percent kill: 7872 mg/kg [Behavioral - Muscle weakness Behavioral - Coma Lungs, Thorax, or Respiration - Respiratory depression] (RTECS)
Diglycidyl Ether of Bisphenol A :
Eye: Administration into the eye - Rabbit Standard Draize test: 2 mg/24H [Severe] (RTECS)
Skin: Administration onto the skin - Rabbit LD50 - Lethal dose, 50 percent kill: 20 gm/kg [Behavioral - Somnolence (general depressed activity) Gastrointestinal - Hypermotility, diarrhea Nutritional and Gross Metabolic - Weight loss or decreased weight gain] (RTECS)
Ingestion: Oral - Rat LD50 - Lethal dose, 50 percent kill: 11300 uL/kg [Details of toxic effects not reported other than lethal dose value] (RTECS)
Hydroquinone :
Skin: Administration onto the skin - Rabbit LD50 - Lethal dose, 50 percent kill: >2000 mg/kg/24H [Details of toxic effects not reported other than lethal dose value] (RTECS)
Ingestion: Oral - Rat LD50 - Lethal dose, 50 percent kill: 302 mg/kg [Details of toxic effects not reported other than lethal dose value]
Oral - Rat LD50 - Lethal dose, 50 percent kill: 320 mg/kg [Behavioral - Ataxia Behavioral - Tetany Lungs, Thorax, or Respiration - Dyspnea]
Oral - Rat LD50 - Lethal dose, 50 percent kill: 367.3 mg/kg [Behavioral - Tremor Blood - Other changes] (RTECS)
SECTION 12 : ECOLOGICAL INFORMATION
Ecotoxicity:
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
SECTION 13 : DISPOSAL CONSIDERATIONS
Description of waste:
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines.
RCRA Number: D001
Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may spontaneously catch fire if improperly discarded or stored. To avoid a spontaneous combustion fire, immediately after use, place rags, steel wool or waste in a sealed, water-filled, metal container.
SECTION 14 : TRANSPORT INFORMATION
DOT Shipping Name: Refer to Bill of Lading
DOT UN Number: Refer to Bill of Lading
IATA Shipping Name: Refer to Bill of Lading
IATA UN Number: Refer to Bill of Lading
IMDG UN Number : Refer to Bill of Lading
IMDG Shipping Name : Refer to Bill of Lading
SECTION 15 : REGULATORY INFORMATION
Safety, health and environmental regulations specific for the product:
Methacrylic acid :
TSCA Inventory Status: Listed
Canada DSL: Listed
Methyl Methacrylate Monomer :
TSCA Inventory Status: Listed
Section 313: EPCRA - 40 CFR Part 372 - (SARA Title III) Section 313 Listed Chemical.
Canada DSL: Listed
Chlorosulfonated polyethylene :
TSCA Inventory Status: Listed
Canada DSL: Listed
Magnesium silicate hydrate :
TSCA Inventory Status: Listed
Canada DSL: Listed
Diglycidyl Ether of Bisphenol A :
TSCA Inventory Status: Listed
Canada DSL: Listed
Hydroquinone :
TSCA Inventory Status: Listed
Section 302 EHS: EPCRA (SARA Title III) Section 302 (40 CFR Part 355) Extremely Hazardous Substances (EHS) Threshold Planning Quantity (TPQ) in pounds.: 500/10,000
Section 313: EPCRA - 40 CFR Part 372 - (SARA Title III) Section 313 Listed Chemical.
Canada DSL: Listed
Canadian Regulations. WHMIS Hazard Class(es): B2; D2B
All components of this product are on the Canadian Domestic Substances List.
WHMIS Pictograms:
SECTION 16 : ADDITIONAL INFORMATION
HMIS Ratings:
HMIS Health Hazard: 2*
HMIS Fire Hazard: 3
HMIS Reactivity: 2
HMIS Personal Protection: X
Health Hazard    2*
Fire Hazard    3
Reactivity    2
Personal Protection    X
*  Chronic Health Effects
SDS Revision Date: May 25, 2015
MSDS Revision Notes: GHS Update
MSDS Author: Actio Corporation
Disclaimer: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. ITW Polymers Adhesives, NA, MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the ITW Polymers Adhesives, NA product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a ITW Polymers Adhesives, NA product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the ITW Polymers Adhesives, NA product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. ITW Polymers Adhesives, NA provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, ITW Polymers Adhesives, NA makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from ITW Polymers Adhesives, NA
 
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